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ChemInform Abstract: Carbonylation of Vinyl Aromatics: Convenient Regioselective Synthesis of 2-Arylpropanoic Acids.

✍ Scribed by A. Seayad; S. Jayasree; R. V. Chaudhari

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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## Abstract Monoamination of dibromopyridines (I) and (VIII) followed by carbonylation and subsequent hydrolysis of methyl esters (VI) and (X) furnish (alkylamino)pyridinecarboxylic acids (VII) and (XI) in satisfactory to good yields, though the 3,5‐dibromopyridine (VIII) reacts more slowly.