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ChemInform Abstract: Carbon—Halogen Bond Activation by Nickel Catalyst: Synthesis of Alkenes, from 1,2-Dihalides.

✍ Scribed by C. MALANGA; S. MANNUCCI; L. LARDICCI

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Carbon-Halogen Bond Activation by Nickel Catalyst: Synthesis of Alkenes, from 1,2-Dihalides.

-1,2-Dihalides are easily converted to unsaturated hydrocarbons or halides in relation to the nature of precursors and hydride donors used (Bu 3 SnH or LiBEt 3 H). The reaction is effectively catalyzed by NiCl 2 (dppe).

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