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ChemInform Abstract: Carbon-Carbon Bond Formation by Catalytic Enantioselective Conjugate Addition

โœ Scribed by B. L. FERINGA; H. M. DE VRIES

Book ID
112037106
Publisher
John Wiley and Sons
Year
2010
Weight
23 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Catalytic Enantiose
ChemInform Abstract: Catalytic Enantioselective Carbonโ€”Carbon Bond Formation by Addition of Dialkylzinc Reagents to Cyclic 1,3-Diene Monoepoxides.
โœ F. BADALASSI; P. CROTTI; F. MACCHIA; M. PINESCHI; A. ARNOLD; B. L. FERINGA ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 29 KB ๐Ÿ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โ€œFull Textโ€ option. The original article is trackable v

Catalytic enantioselective carbon๎—ธcarbon
Catalytic enantioselective carbon๎—ธcarbon bond formation by addition of dialkylzinc reagents to cyclic 1,3-diene monoepoxides
โœ Fabrizio Badalassi; Paolo Crotti; Franco Macchia; Mauro Pineschi; Alexander Arno ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 228 KB

Chiral copper complexes of 2,2'-binaphthyl-based phosphorus amidites are shown to be highly effective catalysts for the conjugate addition of dialkylzine reagents to vinyloxiranes. The corresponding allylic alcohol reaction products (SN2'-pathway) were obtained with moderate to high regioselectivity