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ChemInform Abstract: Carbohydrate Based IMDA/Aldol Strategy Towards the Densely Functionalized trans-Decalin Subunit of Azadirachtin.

✍ Scribed by Dieter Haag; Xiao-Tao Chen; Bert Fraser-Reid


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Carbohydrate Based IMDA/Aldol Strategy Towards the Densely Functionalized trans-Decalin Subunit of Azadirachtin.

-Key steps in the synthesis of the title compound (XII) are the Claisen aldol addition of the aldehyde (V) to the triene (VI) and the intramolecular Diels-Alder reaction of the highly functionalized adducts such as (XII). -(HAAG, DIETER; CHEN,