ChemInform Abstract: Carbene Adduct of Cyclopalladated Ferrocenylimine Catalyzed α-Arylation of Ketones with Aryl Chlorides or Bromides.

✍ Scribed by Jinli Zhang; Xueqian Yang; Xiuling Cui; Yangjie Wu

• Publisher: John Wiley and Sons
• Year: 2012
• Weight: 32 KB
• Volume: 43
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201211055

✦ Synopsis

Abstract

A variety of aryl chlorides and bromides, including unactivated and sterically hindered halides, successfully undergoes α‐arylation of aryl alkyl ketones as well as cyclic ketones in the presence of a novel ferrocenylimine—Pd(II)—NHC ligand.