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ChemInform Abstract: C2-Symmetric Copper(II) Complexes as Chiral Lewis Acids. Catalytic Enantioselective Aldol Additions of Enolsilanes to Pyruvate Esters.

✍ Scribed by D. A. EVANS; M. C. KOZLOWSKI; C. S. BURGEY; D. W. C. MACMILLAN

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199749039

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✦ Synopsis

1997 stereochemistry stereochemistry (general, optical resolution) O 0030 49 -039 C2-Symmetric Copper(II) Complexes as Chiral Lewis Acids. Catalytic Enantioselective Aldol Additions of Enolsilanes to Pyruvate Esters.

-The first catalytic enantioselective addition of enolsilanes to pyruvate esters is described and proceeds with high enantioselectivity.

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