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ChemInform Abstract: C-Glycosides and C-Disaccharide Precursors Through Carbonylative Stille Coupling Reactions.

✍ Scribed by V. JEANNERET; L. MEERPOEL; P. VOGEL


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


C-Glycosides and C-Disaccharide Precursors Through Carbonylative Stille Coupling Reactions. -Suitably protected stannylglucal derivatives (cf. (I)) undergo a carbonylative Stille coupling reaction with the bromides (II) in the presence of Pd(0) catalysts and Ph3As. The reaction is also successful with the iodoglucal (VI) providing the C-disaccharide (VII). Furthermore, vinylstannanes such as (VIII) lead to the carbonylative heterocoupling products (IX).


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