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ChemInform Abstract: Butylstannonic Acid Catalyzed Transesterification of Carboxylic Esters.

✍ Scribed by R. L. E. FURLAN; E. G. MATA; O. A. MASCARETTI

Publisher
John Wiley and Sons
Year
2010
Weight
42 KB
Volume
29
Category
Article
ISSN
0931-7597

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The lipase-catalyzed irreversible transesterification procedure using vinyl esters was applied to the resolution of racemic 2-phenoxypropanoic acids. Aspergillus niger lipase showed high enantioselectivities and reasonable reaction rates. The enantioselectivity was found to be affected profoundly by