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ChemInform Abstract: Bu3SnH-Mediated Pinacol Coupling of 1,5- and 1,6-Dicarbonyl Compounds: Synthetic and Mechanistic Studies.

✍ Scribed by D. S. HAYS; G. C. FU

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Bu 3 SnH-Mediated Pinacol Coupling of 1,5-and 1,6-Dicarbonyl Compounds: Synthetic and Mechanistic Studies.

-A new method employing Bu 3 SnH as the stoichiometric reductant to effect the intramolecular cyclization of the title compounds is presented. 1,5-Dicarbonyl compounds like (I) and (III) show a very high cis selectivity in this cyclization. -(HAYS,

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