ChemInform Abstract: Biphenyl-Based Diaminophosphine Oxides as Air-Stable Preligands for the Nickel-Catalyzed Kumada—Tamao—Corriu Coupling of Deactivated Aryl Chlorides, Fluorides, and Tosylates.

Biphenyl-Based Diaminophosphine Oxides a

Biphenyl-Based Diaminophosphine Oxides as Air-Stable Preligands for the Nickel-Catalyzed Kumada–Tamao–Corriu Coupling of Deactivated Aryl Chlorides, Fluorides, and Tosylates

✍ Prof. Dr. Zhong Jin; Yan-Jing Li; Prof. Dr. Yong-Qiang Ma; Ling-Ling Qiu; Prof. 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 295 KB

Transition-metal-catalyzed cross-coupling reactions [1] of aryl halides or pseudo-halides with organometallic reagents, such as Grignard reagents, organozinc compounds, boronic acids, organostannanes, and organosiloxanes, are powerful tools for the synthesis of the biaryl motif, which is prevalent i