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ChemInform Abstract: Biomimetic Oxidation of Organic Substrates by Chemical Models of Cytochrome P-450 and Related Heme Monooxygenases

✍ Scribed by S. M. S. CHAUHAN

Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Abstract Kinetic and mechanistic studies on the formation of an oxoiron(IV) porphyrin cation radical bearing a thiolate group as proximal ligand are reported. The **SR** complex, a functional enzyme mimic of P450, was oxidized in peroxo‐shunt reactions under different experimental conditions wit