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ChemInform Abstract: Bimolecular Reactions of Alkyl Halides and Acylgermanes: Formation of Ketones, Diketones, and Other Products by Radical-Radical Reaction.

✍ Scribed by U. DIEDERICHSEN; D. P. CURRAN

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Bimolecular Reactions of Alkyl Halides and Acylgermanes: Formation of Ketones, Diketones, and Other Products by Radical-Radical Reaction.

-The photolytic addition of alkyl iodides to acylgermanes produces mixtures of ketones and diketones. However, the yields are very low and other products such as alkanes and alkenes are also formed. The formation of radical-radical products, the lack of reaction when using thermal initiation conditions suggest that bimolecular addition reaction of alkyl radicals to acylgermanes are too slow to propagate radical chains. - (DIEDERICHSEN,

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