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ChemInform Abstract: Bicyclo(1.1.1)pent-1-yl: A Tertiary Alkyl Radical with Enhanced Reactivity.

✍ Scribed by J. T. BANKS; K. U. INGOLD; E. W. DELLA; J. C. WALTON

Publisher: John Wiley and Sons
Year: 2010
Weight: 24 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199707062

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✦ Synopsis

Bicyclo(1.1.1)pent-1-yl: A Tertiary Alkyl Radical with Enhanced Reactivity.

-Kinetic measurements clearly indicate that the bridgehead title radical is considerably more reactive than the tert-butyl radical. The enhanced reactivity is attributed to its high s-character and the absence of steric shielding of the radical center. -(BANKS,

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