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ChemInform Abstract: Benzylic-Acetoxylation of Alkylbenzenes with PhI(OAc)2 in the Presence of Catalytic Amounts of TsNH2 and I2

✍ Scribed by Haruka Baba; Katsuhiko Moriyama; Hideo Togo

Publisher: John Wiley and Sons
Year: 2011
Weight: 41 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201148033

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✦ Synopsis

Abstract

The introduction of an acetoxy or benzoyloxy group to the benzylic position of alkylbenzenes is achieved using hypervalent iodine compounds (II) in the presence of iodine and sulfonamides.

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