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ChemInform Abstract: Benzyl Cation Initiated Intramolecular Cyclizations. Synthesis of 1-Azabicyclo[3.2.1]octene Derivatives.

✍ Scribed by E. CSUZDI; I. PALLAGI; I. SZIRAKI; S. SOLYOM


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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## Abstract Intramolecular cyclization reactions were performed with 1‐(3‐oxo‐2‐phenylbutyl)‐1,2,5,6‐tetrahydropyridine derivatives 6a‐h in sulfuric acid to give 3,6‐diphenyl‐substituted 1‐aza‐bicyclo[3.3.1]nonadienes 9. The intermediate carbinols 7a‐f and 8b, c could be isolated. Carrying out the