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ChemInform Abstract: Benzoanellated cis,cis,cis,trans-[5.5.5.6]Fenestranes: Syntheses, Base Lability, and Flattened Molecular Structure of Strained Epimers of the all-cis Series.

✍ Scribed by Bjoern Bredenkoetter; Ulrich Floerke; Dietmar Kuck


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
33
Category
Article
ISSN
0931-7597

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Abstract

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Benzoannelated cis,cis,cis,trans-[5.5.5.
✍ Björn Bredenkötter; Ulrich Flörke; Dietmar Kuck 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 272 KB 👁 2 views

Tribenzofenestranes possessing the strained cis,cis,cis,trans-[5.5.5.6]fenestrane skeleton have been synthesized from cis-2,6-diphenylspiro[cyclohexane-1,2'-indane]-1',3'-diols by twofold cyclodehydration, in striking analogy to the strategy used previously to construct the stereoisomeric all-cis-tr