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ChemInform Abstract: BaM(BS3)S (M: Sb, Bi): Two New Thioborate Compounds with One-Dimensional Polymeric Chain Structure.

✍ Scribed by Lei Geng; Wen-Dan Cheng; Wei-Long Zhang; Chen-Sheng Lin; Hao Zhang; Ye-Yu Li; Zhang-Zhen He


Publisher
John Wiley and Sons
Year
2010
Weight
16 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The title compounds are prepared by solid state reactions of BaS, Bi (or Sb), B, and S in the molar ratios of 1:1:1:3 (graphite crucibles, 1100 K, 10 h) and characterized by single crystal XRD, UV/VIS spectroscopy, and DFT electronic structure calculations.