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ChemInform Abstract: BaCu10P4: A New Structure Composed of Chains of Edge-Shared Cu4 Tetrahedra.

✍ Scribed by D. M. YOUNG; J. CHARLTON; M. M. OLMSTEAD; S. M. KAUZLARICH; C.-S. LEE; G. J. MILLER

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199735016

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✦ Synopsis

BaCu10P4: A New Structure Composed of Chains of Edge-Shared Cu4 Tetrahedra.

-The novel title compound is prepared in quantitative yield by heating of stoichiometric mixtures of the elements at 1200 • C. The structure (monoclinic, C2/m, Z = 4), determined by powder and singlecrystal XRD methods, represents a new type of chains of edge-sharing Cu4 tetrahedral prisms, which are connected by P atoms. The metallic character, shown by temp.-dependent resistivity measurements, is confirmed by extended Hueckel band structure calculations. -(YOUNG, D. M.;

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