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ChemInform Abstract: Ba4Si3Br2: A Double Salt of Barium Bromide and Barium Silicide Containing a Novel Cyclotrisilicide Unit.

โœ Scribed by Steffen Wengert; Johannes B. Willems; Reinhard Nesper


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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Ba4Si3Br2: A Double Salt of Barium Bromi
โœ Steffen Wengert; Johannes B. Willems; Reinhard Nesper ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 134 KB

A new compound of the composition Ba 4 Si 3 Br 2 was obtained by reacting BaSi with a melt of BaBr 2 . Ba 4 Si 3 Br 2 may be described as a double salt between a Zintl phase and a halide. The structure was determined by singlecrystal X-ray diffraction (P2 1 c, a 1504.1(2), b 884.5(1), c 880.2(1) pm,