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ChemInform Abstract: Azido-Phenylselenylation of 3-O-Benzyl-2-deoxy-5,6-O-isopropylidene-D- arabino-1,4-anhydro-hex-1-enitol: Convenient Preparation of 2-Azido-2- deoxy-D-glucofurano- and glucopyranoside Donors.

โœ Scribed by E. CHELAIN; S. CZERNECKI; M. CHMIELEWSKI; Z. KALUZA

Book ID
112040221
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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Synthesis and Glycosidic Coupling Reaction of Substituted 2,6-Dioxabicyclo[3.1.1]heptanes: 1,3-Anhydro-2-azido-4,6-di-O-benzyl-2deoxy-ฮฒ-D-mannopyranose. -The title sugar (VII) is synthesized via the key intermediate (VI) starting from glucopyranoside (I). Anhydrosugar (VII) is quite reactive: ring-