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ChemInform Abstract: Atropo-Enantioselective Synthesis of a Simplified Analogue of Mastigophorenes A and B.

✍ Scribed by G. BRINGMANN; T. PABST; S. BUSEMANN; K. PETERS; E.-M. PETERS

Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Atropo-Enantioselective Synthesis of a Simplified Analogue of Mastigophorenes A and B. -A first approach towards the atroposelective total synthesis of mastigophorenes (XIII), sesquiterpenoid biaryl natural products with nerve growth and network formation stimulating activity, is presented. Key step in this synthesis is the atropo-diastereoselective ring opening of the stereochemically labile lactone (VI). -(BRINGMANN, G.;

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