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ChemInform Abstract: Asymmetric Trienamine Catalysis for the Construction of Structurally Rigid Cyclic α,α-Disubstituted Amino Acid Derivatives.

✍ Scribed by Hao Jiang; Bjoern Gschwend; Lukasz Albrecht; Signe Grann Hansen; Karl Anker Joergensen

Publisher: John Wiley and Sons
Year: 2011
Weight: 43 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201152123

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✦ Synopsis

Abstract

In the presence of a secondary amine catalyst, 2,4‐dienals undergo highly regio‐ and stereoselective Diels—Alder reactions with olefinic azlactones.

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