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ChemInform Abstract: Asymmetric Synthesis Using Sulfinimines (Thiooxime S-Oxides)

✍ Scribed by F. A. DAVIS; P. S. PORTONOVO; R. E. REDDY; P. ZHOU


Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Synthesi
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

ChemInform Abstract: Asymmetric Synthesi
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The diastereomerically pure sulfinylating reagent (III) reacts with nucleophilic Grignard reagents or the zinc reagent derived from (VI) to yield chiral sulfoxides with excellent yields and enantioselectivities. Under specific conditions sequential reaction of (III) with LiN(Tms)2 followed by aldehy