ChemInform Abstract: Asymmetric Synthesis of Functionalized Benzo(a)quinolizine Derivatives via a Diastereoselective N-Acyliminium Ion Cyclization.
β Scribed by Y. S. LEE; S. S. KANG; J. H. CHOI; H. PARK
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Synthesis of Enantiopure Functionalized Pipecolic Acids via Amino Acid Derived N-Acyliminium Ions. -N-Acyliminium ion cyclization of various non-natural olefinic amino acids (VII), (X), (XV), and (XX) in the presence of nucleophiles affords enantiopure functionalized pipecolic acids in moderate yie