The enantiomerically pure glycine derivative tert-butyl (S)-2-(tert-butyl)-3-methyl-4-oxo-l-imidazolidinecarboxylate (Boc-BMI) reacts with (Z)-l,4-dichloro-2butene and 3-chloro-2-(chloromethyl)-1-propene to give the bicyclic intermediates 5 and 6, respectively. These dialkylated systems are hydrolyz
✦ LIBER ✦
ChemInform Abstract: Asymmetric Synthesis of Cyclic α-Amino Acids (-)-Baikiain (IV) and (-)-4-Methyleneproline (VII) from (S)-Boc-BMI.
✍ Scribed by A. MAZON; C. NAJERA
- Book ID
- 101856140
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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