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ChemInform Abstract: Asymmetric Organocatalytic Electrophilic Phosphination.

✍ Scribed by Martin Nielsen; Christian Borch Jacobsen; Karl Anker Joergensen

Publisher
John Wiley and Sons
Year
2011
Weight
49 KB
Volume
42
Category
Article
ISSN
0931-7597

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Scheme 1. One-pot electrophilic phosphination and formation of aquaternary a-phosphino b-amino esters 4 by an asymmetric organocatalytic key step. Boc = tert-butoxycarbonyl.

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## Abstract Depending on catalyst and reducing agent used, selective formation of (R)‐ or (S)‐ and (E)‐ or (Z)‐configurated products is possible.