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ChemInform Abstract: Asymmetric Molybdenum-Catalyzed Alkylations.

✍ Scribed by B. M. TROST; I. HACHIYA

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✦ Synopsis

1998 stereochemistry stereochemistry (general, optical resolution) O 0030

Asymmetric Molybdenum-Catalyzed Alkylations.

-An excellent approach for regio-and enantioselective alkylations of the more substituted terminus of cinnamyl-like systems is presented.

The molybdenum-ligand complex used in these alkylations is proposed to have a trans-bridged structure.

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