Catalytic Asymmetric Synthesis of syn-Aldol Products from Intermolecular C-H Insertions Between Allyl Silyl Ethers and Methyl Aryldiazoacetates. -The simple allyloxy derivative (I) undergoes a Rh-catalyzed reaction with 4-chlorophenyldiazoacetate (II) to give the cyclopropane (III). The allyl silyl
✦ LIBER ✦
ChemInform Abstract: Asymmetric Intramolecular C—H Insertions of Aryldiazoacetates.
✍ Scribed by Huw M. L. Davies; Monica V. A. Grazini; Emmanuel Aouad
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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