ChemInform Abstract: Asymmetric Inter- and Intramolecular Cyclopropanation Reactions Catalyzed by a Reusable Macroporous-Polymer-Supported Chiral Ruthenium(II)/Phenyloxazoline Complex.

✍ Scribed by Abdel-Moneim Abu-Elfotoh; Kesiny Phomkeona; Kazutaka Shibatomi; Seiji Iwasa

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 52 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201112052

✦ Synopsis

Abstract

The novel heterogeneous Ru‐complex is highly efficient in the preparation of trans‐cyclopropanes such as (III) and (V), which are formed in most cases with excellent diastereoselectivity and enantioselectivity.