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ChemInform Abstract: Asymmetric Hydrolysis of α-Alkylated Cyclohexanone Enol Acetates by the Cultured Cells of Marchantia polymorpha.

✍ Scribed by T. HIRATA; K. SHIMODA; D. OHBA; N. FURUYA; S. IZUMI


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Asymmetric Hydrolysis of α-Alkylated Cyclohexanone Enol Acetates by the Cultured Cells of Marchantia polymorpha.

-Cultured suspension cells of Marchantia polymorpha hydrolyze 2-alkyl-substituted cyclohexanone enol acetates to afford optically active ketones. A reversal of stereoselectivity with increasing chain length of the alkyl substituents is observed. -(HIRATA, T.;