ChemInform Abstract: Asymmetric Hetero Diels—Alder Reaction of Homochiral Thiabutadienes, 3-(Arylmethylene)thiocamphors.
✍ Scribed by Takao Saito; Junichi Nishimura; Daisuke Akiba; Hiroshi Kusuoku; Kimiko Kobayashi
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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Asymmetric Hetero-Diels-Alder Reactions with Heterocumulenes. -Chiral 2-alkenyloxazolines or thiazolines (I) and (IV) undergo hetero-Diels-Alder reaction with the ketene (II) or the isocyanate (VI) giving adducts with complete stereocontrol. In the case of oxazoline (I) a fast second addition yield
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