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ChemInform Abstract: Asymmetric Direct Alkynylation Catalyzed by Chiral Ru—Bis(oxazolinyl)phenyl Complexes.

✍ Scribed by Jun-ichi Ito; Ryosuke Asai; Hisao Nishiyama

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
41
Category
Article
ISSN
0931-7597

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Ru(II)-Catalyzed Asymmetric Cyclopropanation Using Chiral Diphenylphosphino(oxazolinyl)quinoline Ligands. -N,N,P-chelates (I) are investigated as chiral ligands in intermolecular and intramolecular asymmetric Ru-catalyzed cyclopropanation reactions. A dramatic influence of the oxazoline ring substi