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ChemInform Abstract: Asymmetric Direct Aldol Reaction of α-Keto Esters and Acetone Catalyzed by Bifunctional Organocatalysts.

✍ Scribed by Fei Wang; Yan Xiong; Xiaohua Liu; Xiaoming Feng

Publisher
John Wiley and Sons
Year
2008
Weight
34 KB
Volume
39
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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## Abstract A type of __C~2~__‐symmetrical bisprolinamide has been developed for the asymmetric aldol reaction between acetone and α‐keto esters, which furnishes the chiral tertiary alcohols in high yields (up to 99 %) with high enantioselectivities (up to 94 % __ee__). Aliphatic, heteroaromatic an

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