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ChemInform Abstract: Asymmetric Cyclopropanations by Rhodium(II) N-(Arylsulfonyl)prolinate Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Alkenes. Practical Enantioselective Synthesis of the Four Stereoisomers of 2-Phenylcyclopropan-1-amino Acid.

✍ Scribed by H. M. L. DAVIES; P. R. BRUZINSKI; D. H. LAKE; N. KONG; M. J. FALL

Book ID: 112039795
Publisher: John Wiley and Sons
Year: 2010
Weight: 36 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199645107

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Asymmetric Cyclopropanations by Rhodium(

Asymmetric Cyclopropanations by Rhodium(II) N-(Arylsulfonyl)prolinate Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Alkenes. Practical Enantioselective Synthesis of the Four Stereoisomers of 2-Phenylcyclopropan-1-amino Acid

✍ Davies, Huw M. L.; Bruzinski, Paul R.; Lake, Debra H.; Kong, Norman; Fall, Micha 📂 Article 📅 1996 🏛 American Chemical Society 🌐 English ⚖ 476 KB

ChemInform Abstract: Enantioselective Sy

ChemInform Abstract: Enantioselective Synthesis of Functionalized Tropanes by Rhodium(II) Carboxylate-Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Pyrroles.

✍ H. M. L. DAVIES; J. J. MATASI; L. M. HODGES; N. J. S. HUBY; C. THORNLEY; N. KONG 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 1 views

## Enantioselective Synthesis of Functionalized Tropanes by Rhodium(II) Carboxylate-Catalyzed Decomposition of Vinyldiazomethanes in the Presence of Pyrroles. -A number of enantiomerically enriched tropones can be prepared efficiently using the title method. The reaction proceeds via a tandem cycl