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ChemInform Abstract: Asymmetric Creation of Quaternary Carbon Centers by Enantiotopically Selective Aromatic C-H Insertion Catalyzed by Chiral Dirhodium(II) Carboxylates.

✍ Scribed by N. WATANABE; Y. OHTAKE; S. HASHIMOTO; M. SHIRO; S. IKEGAMI


Book ID
112023035
Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
26
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Highly Enantioselec
✍ M. ANADA; N. WATANABE; S. HASHIMOTO πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 42 KB πŸ‘ 2 views

Highly Enantioselective Construction of the Key Azetidin-2-ones for the Synthesis of Carbapenem Antibiotics via Intramolecular C-H Insertion Reactions of Ξ±-Methoxycarbonyl-Ξ±-diazoacetamides Catalyzed by Chiral Dirhodium(II) Carboxylates. -The title reaction of compounds (I) and (III) to afford bicy