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ChemInform Abstract: Asymmetric Conjugate Addition to Cyclic Enone Catalyzed by Cu-NHC Complexes with C2 Symmetry.

✍ Scribed by Fengjun Shan; Lan Jiang; Zhengning Li; Defeng Zhao

Publisher: John Wiley and Sons
Year: 2011
Weight: 27 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201138028

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✦ Synopsis

Abstract

If cyclopent‐2‐enone (IV) instead of cyclohex‐2‐enone (I) is used for the title reaction, the stereochemistry is reversed and the enantioselectivity is much lower.

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