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ChemInform Abstract: Asymmetric Chemical Oxidations of Aryl and Alkyl 2-(Trimethylsilyl) ethyl Sulfides.

โœ Scribed by A. L. SCHWAN; M. F. PIPPERT


Book ID
112022947
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
26
Category
Article
ISSN
0931-7597

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Asymmetric epoxidation of aliphatic enones can be achieved with good conversions and high levels of enantiomeric excess using a catalyst, formulated as 6, derived from dibutylmagnesium and a range of dialkyl tartrates, with tert-butylhydroperoxide as the oxidant. This process works best with the add