Catalytic Asymmetric Synthesis of syn-Aldol Products from Intermolecular C-H Insertions Between Allyl Silyl Ethers and Methyl Aryldiazoacetates. -The simple allyloxy derivative (I) undergoes a Rh-catalyzed reaction with 4-chlorophenyldiazoacetate (II) to give the cyclopropane (III). The allyl silyl
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ChemInform Abstract: Asymmetric Catalytic C—H Activation Applied to the Synthesis of syn-Aldol Products.
✍ Scribed by Huw M. L. Davies; Evan G. Antoulinakis
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 31 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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