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ChemInform Abstract: Asymmetric Catalysis via Dynamic Substrate/Ligand/Rare Earth Metal Conglomerate.

✍ Scribed by Akihiro Nojiri; Naoya Kumagai; Masakatsu Shibasaki

Publisher: John Wiley and Sons
Year: 2008
Weight: 61 KB
Volume: 39
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200833092

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✦ Synopsis

Abstract

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## Abstract Fused as well as alkyl‐disubstituted aziridines undergo ring opening under catalysis of a complex derived from a 1:1:1 mixture of Broensted basic alkoxide La(OiPr)~3~, Lewis acidic triflate Yb(OTf)~3~, and axially chiral Schiff base BBN.