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ChemInform Abstract: Asymmetric Carbon—Carbon Bond Formation in Michael Reactions: Conjugate Addition Reactions of Configurationally Stable Benzylic and Allylic Organolithium Species.

✍ Scribed by M. D. Curtis; P. Beak

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Conjugate Addition Reactions of Configurationally Stable Benzylic and Allylic Organolithium Species.

-The organolithium species generated from the amines (I) and (IV), BuLi, and (-)-sparteine react with double activated olefins and nitro olefins to provide addition products in good yields with high enantioselectivity at both termini of the newly formed bond.

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