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ChemInform Abstract: Asymmetric Arylation of Ketone Enolates.

✍ Scribed by J. AAHMAN; J. P. WOLFE; M. V. TROUTMAN; M. PALUCKI; S. L. BUCHWALD

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199825052

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## Abstract Palladium‐catalyzed asymmetric allylic alkylation of nonstabilized ketone enolates to generate quaternary centers has been achieved in excellent yield and enantioselectivity. Optimized conditions consist of performing the reaction in the presence of two equivalents of LDA as base, one e