ChemInform Abstract: Asymmetric Aldol-Tishchenko Reaction Catalyzed by Yb-Complexes with Basic Amino Acid-Derived Ligands.

✍ Scribed by Maciej Stodulski; Agnieszka Maminska; Jacek Mlynarski

• Publisher: John Wiley and Sons
• Year: 2011
• Weight: 30 KB
• Volume: 42
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.201135078

✦ Synopsis

Abstract

The title reaction of aromatic aldehydes with aliphatic ketones affords 1,3‐diols with complete 1,2‐anti‐1,3‐anti diastereoselectivity and enantioselectivities up to 50%.