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ChemInform Abstract: Aqueous NaHSO4 Catalyzed Regioselective and Versatile Synthesis of 2-Thiazolamines.

✍ Scribed by Shahnaz Rostamizadeh; Reza Aryan; Hamid R. Ghaieni; Ali M. Amani


Publisher
John Wiley and Sons
Year
2009
Weight
25 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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Synthesis of 2,4-Diketoacids and Their Aqueous Solution Structures. -The synthesis of 2,4-diketoacids (IV) and (VII) is achieved by base-mediated condensation of oxalate (I) with methyl ketones (II) and (V) followed by ester hydrolysis. The diketoacids are shown to exist as 2-enols in CHCl 3 soluti