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ChemInform Abstract: Anomeric Samarium(III) Intermediates of N-Acetylneuraminic Acid from Anomeric 2-Pyridylsulfides.

✍ Scribed by Adeline Malapelle; Zouleika Abdallah; Gilles Doisneau; Jean-Marie Beau


Publisher
John Wiley and Sons
Year
2009
Weight
35 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Diastereocontrolled
✍ I. R. VLAHOV; P. I. VLAHOVA; R. J. LINHARDT πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 2 views

Diastereocontrolled Synthesis of Carbon Glycosides of N-Acetylneuraminic Acid via Glycosyl Samarium(III) Intermediates. -Treatment of the sulfone derivatives of N-acetylneuraminic acid such as (I) and (III) with SmI2 generates in situ neuraminyl-Sm(III) species due to the reducing potential of SmI2