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ChemInform Abstract: Anomalous Role of Molecular Sieves 4A in the Preparation of a Binaphthol-Derived Active μ3-Oxo Titanium Catalyst.

✍ Scribed by M. TERADA; Y. MATSUMOTO; Y. NAKAMURA; K. MIKAMI

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199726123

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✦ Synopsis

Anomalous Role of Molecular Sieves 4A in the Preparation of a Binaphthol-Derived Active µ3-Oxo Titanium Catalyst.

-The role of molecular sieves in the catalytic system (R)-BINOL/TiCl2( OiPr)2/mol. sieves is investigated using the glyoxylate-ene reaction as example. The molecular sieves act as H2O donor for the catalytic system. -(TERADA,

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