Synthesis and Glycosylation of Thio-D-fructofuranoside Donors. -Ethylthioglycosides (I) are prepared from D-arabinose. They readily react with bulky alcohol acceptors in the presence of IDCP to give only ฮฑ-fructofuranosides in high yield. -(LI, Y.-L.;
โฆ LIBER โฆ
ChemInform Abstract: Analogues of D-Glucosaminylphosphatidylinositol: Synthesis of the Glycosyl Donors.
โ Scribed by Alexander P. Dix; Charles N. Borissow; Michael A. J. Ferguson; John S. Brimacombe
- Publisher
- John Wiley and Sons
- Year
- 2001
- Weight
- 25 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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First Synthesis of Anomeric Sulfimides -Efficient Glycosyl Donors. -Carbohydrate-derived sulfimides of type (III) are efficiently prepared by reaction of the corresponding thioglycosides with chloramine T. They are investigated as glycosyl donors with a variety of alcohols. In several cases the ano