ChemInform Abstract: An Intramolecular Pauson—Khand Approach to the Synthesis of Chiral Cyclopentadienes.
✍ Scribed by Ramon Rios; Albert Moyano; Miquel A. Pericas
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
## Abstract A number of propargylic alcohols is prepared with high enantioselectivity.
Pauson-Khand Approach to Chiral, Diastereomerically Pure Group 4 ansa-Metallocene Complexes. -Dienediynes (IIIa) and (IIIb), readily prepared from tosylates (I) by alkylation with lithioalkynes (II), are converted to diastereopure Pauson-Khand (P-K) products (V) by reaction with Co 2 (CO) 8 , where
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