✍ Scribed by P. JONES; W.-S. LI; G. PATTENDEN; N. M. THOMSON
No coin nor oath required. For personal study only.
An Exploration of the Scope for Radical-Mediated Transannular Diels-Alder Reactions in Polycycle Synthesis.
-Radical-mediated cyclization of the ynone substrates (I), (III), and (V) leads to formation of different types of polycyclic compounds. Reaction mechanisms are proposed.
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Trifluoromethanesulfonic Acid, an Efficient Catalyst for the Hetero Diels-Alder Reaction and an Improved Synthesis of Mefrosol. -The hetero Diels-Alder reaction between unactivated dienes with alkyl groups in the 2-position (cf. isoprene (II)) and aromatic aldehydes is effectively promoted by catal
Control of Stereochemistry in an Intramolecular Diels-Alder Reaction by the Phenylsulfonyl Group: An Improved Synthesis of Pisiferol. -An improved approach to the known intermediate (VII) of the pisiferol synthesis is established by use of the title group in the intramolecular Diels-Alder reaction l
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