✦ LIBER ✦
ChemInform Abstract: An Ester Enolate—Claisen Rearrangement Route to Substituted 4-Alkylideneprolines. Studies Toward a Definitive Structural Revision of Lucentamycin A.
✍ Scribed by Sujeewa Ranatunga; Jinsoo S. Kim; Ujjwal Pal; Juan R. Del Valle
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 71 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
In the presence of NaN(Tms)~2~, esters of type (I) and (IX) rearrange to amino acids like (II) and (X) with moderate to high diastereoselectivity.