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ChemInform Abstract: An Enantioselective Epoxide Rearrangement - Claisen Rearrangement Approach to Prostaglandins and (+)-Iridomyrmecin.

✍ Scribed by D. M. HODGSON; A. R. GIBBS


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Enantioselective Ar
✍ H. ITO; A. SATO; T. TAGUCHI πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 2 views

Enantioselective Aromatic Claisen Rearrangement. -Allylic aromatic ethers bearing an (E)-or (Z)-side chain undergo highly enantioselective Claisen rearrangements in the presence of the chiral boron reagent (Ia). The method also avoids the formation of para or abnormal Claisen rearrangement products

ChemInform Abstract: An Epoxide Rearrang
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An Epoxide Rearrangement -Radical Rearrangement Approach to 6-Substituted 2-Azabicyclo[2.2.1]-5-heptenes: Synthesis of an Epibatidine Analogue. -Base-promoted isomerization of the epoxide (I) provides the azanortricyclanol (II). The latter can be readily converted to the derivatives (V) as precurso